Chemistry Co-ordinatios Compounds JEE (Main) / AIEEE Problems (Previous Year) Single Correct MCQ
Published on: August 12, 2026

Among the statements(a)-

A
Octahedral Co(III) complexes with strong field ligands have very high magnetic moments and and
B
When Δ 0 < P, the d-electron configuration of Co(III) in an octahedral complex is and only
C
Wavelength of light absorbed by [Co(en) 3 ] 3+ is lower than that of [CoF 6 ] 3– only and
D
, the incorrect ones are : If the Δ 0 for an octahedral complex of Co(III) is 18,000 cm –1 , the Δ t for its tetrahedral complex with the same ligand will be 16,000 cm –1 only only

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Verified by Experts
The correct answer is:
D

with a strong field complex forms a low magnetic moment complex.
If , the configuration of will be .
CFSE of is more than that of . It implies that absorbed of is less than that of
.

Hence, statements and are incorrect.

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